Zvigadzirwa
Dibziva-18-korona-6; Casha Kwete: 14187-32-7
Synonyms: Dibenzo-18-korona-6; polyether xxviii
Chemical gadzika yeDibenzo-18-korona-6
● Kutaridzika / Ruvara: chena kune zvishoma beige fluffy poda
● Vapor Kumanikidzwa: 3.65e-10mmhg pa 25 ° C
● Rolling Pfungwa: 162-164 ° C (lit.)
● Refractive Index: 1.5
● Boiling Point: 503.1 ° C at 760 mmhg
● Flash Pfungwa: 206 ° C
● PSA:55.38000
● Density: 1.108 g / cm3
● logp: 2.94880
● Kuchengetedza temp.Zvikonzero pazasi + 30 ° C.
● Sensitive.:air inonzwa
● Solubility.:0.007g/l
● Soluluility yemvura. 3.kerekeve zvisina musoro
● XLOGP3: 2.2
● Hydrogen Bond anopa kuverenga: 0
● Hydrogen Bond Anogamuchira Kuverenga: 6
● Rinotenderera Bond Count: 0
● chaiyo misa: 360.15728848
● Anorema Atomu Kuverenga: 26
● kuomarara: mazana matatu
Ruzivo rwekufa
● pikicha (s):
Xi,
Xn
● Hazard Codes: Xi, xn
● Zvirevo: 36-36 / 37 / 38-20 / 21/22
● Zvirevo Zvekuchengetedza: 26-37 / 39-36
Zvinoshanda
Makirasi emakemikari:Mamwe makirasi -> mamwe organic compounds
Canonical kunyemwerera:C1coc2 = CC = CC = C2Ccoccoc3 = CC = CC = C3OCCO
Inoshandisa:Dikezo-18-korona-6, inoshandiswa seyakakosha zvinhu zvisingabati uye zvepakati zvinoshandiswa mune organic synicesis, mishonga, genremicals uye dyestuff. Icho chakakosha organic yepakati. Korona Ether / Dibenzo-18-korona-6 yeSynthesis. CAS 14187-32-7, Molar Misa 360.41 G / Mol.
Tsanangudzo yeruzivo
Dibziva-18-korona-6. Iyo cyclic ether inoumbwa nemakemikari mafomula c20h24o6. Kuwedzerwa kweBenene mhete kune 18-korona-6 inoshandura kugadzikana kwayo uye kushandura zvivakwa zvayo, kugadzira Dibenzo-18-korona-6 yakasarudzika nzvimbo ine zvakasiyana.
Kuvapo kweBenzene Mhete muDibenzo-18-korona-6 inosvitsa kusanzwisisika kune iyo molecule, iyo inogona kukurudzira zvakanyanya makemikari uye yemuviri zvivakwa. Kuwedzera kwemhete idzi kunowedzera maEkiri-conjugation mukati meMorekuru, kugadzira Dibenzo-18-korona - 6 yakaomarara uye isinganyorerwe kuenzaniswa nemubereki, 18-korona-6.
Sumo yezvinonhuwirira moiges muDibhenzo-18-korona - 6 zvakare inoshandura iyo solubility uye kubatana kwemari dzakasiyana. Uku kugadziridzwa kunowanzotungamira kune yakagadziridzwa solubility mu organic soles, kugadzira Dibenzo-18-korona-yakakodzera kune dzakasiyana-siyana zvikumbiro izvo zvisingaite kana zvinetso zvemhando yepamusoro.
Zvakafanana na 18-korona - 6, Dibenzo-18-korona-6-6 inochengetedza kugona kuomarara neesimbi ion, kugadzira yakagadzikana yekudyidzana The presence of the benzene rings can further enhance the selectivity and stability of these metal ion complexes, making dibenzo-18-crown-6 useful in metal ion extraction, separation, sensing, and catalysis, similar to its parent compound.
Dibenzo-18-korona-6's yakawedzera kuomarara uye kugadzikana kunoita kuti zvinyanye kurwisa kusvibiswa kwemazwi kana uchienzaniswa ne18-korona-korona-korona - 6. Iyi ficha inobatsira kushandiswa kwayo mukuwedzera-tembiricha maitiro uye maitiro.
Nepo Dibenzo-18-korona-6 inogovana kufanana ne 18-korona-6, zvimiro zvaro zvakasarudzika zvinokonzeresa zvechemistry dzakasiyana, ion inonzwa, catalinys, uye yakakwirira-tembiricha maitiro. Kuwedzerwa kweBenene mhete kune korona ether chimiro chinowedzera kugadzikana kwayo, zvichishandura maitiro ayo ekushandura, uye anowedzera mashandisiro ayo anogona kushandiswa muminda yakasiyana yemakemikari uye zvigadzirwa zvesainzi.
Application
Dibziva-18-korona-6 (db18c6) ine akati wandei maficha muminda dzakasiyana siyana, kusanganisira:
Metal ion kubviswa uye kupatsanurwa:DB18c6 inonyanya kushanda mukunetseka kwesimbi ion. Kugona kwayo kusarudza kusarudzika neesimbi ion seSodium, potasum, uye amonium, uye maAmonium, uye anobatsira musimbi ion kubviswa kwesimbi uye maitiro ekuparadzanisa. Inogona kushandirwa mune solvent yekubvisa nzira kuti isasarudza kubvisa chaiyo simbi ion kubva musanganiswa.
Supromolecular chemistry:DB18c6 inoshandiswa zvakanyanya mu supromolecular chemistry. Yayo yakasarudzika uye zvivakwa zvinoita kuti zviite kuti zviite kuti zviite kuumba-muenzi-mueni akaomesesa vaenzi vanosiyana-vashoma mamorekuru, kusanganisira madiki madiki mishonga uye simbi ion. Aya maGuest-Guest kuwirirana kunogona kushandiswa pakugadzirwa uye kuvakwa kwemashandisirwo emanyorero emanyorero uye zvigadzirwa.
Ion inonzwa:Nekuda kwekorona yayo Erther chimiro, DB18c6 inogona kusarudza kusunga vamwe ion, inotungamira shanduko mune yayo chaiyo, electrochemical, kana fluorescence zvivakwa. Ichi chivakwa chinoita kuti DB18C6 yakakoshesa ion-inonzwa zvinhu, iyo inogona kushandirwa mukuvandudzwa kweIion sensors uye vanoongorora.
Catalylek:DB18c6 uye zvaro zvaro simbi ion commoces inogona kuita secarts yekusaita kwakasiyana siyana. Zvivakwa zvavo zvakasarudzika zvinopa nharaunda yakakodzera yekufambisa chaiyo kemikari shanduko. DB18c6-based CATALYSTS yakave yakashanda mu organic synthesis, oxidation maitiro, uye zvimwe maitiro ezvekutengesa.
Yakakwira-tembiricha maitiro: kudzikisira kugadzikana uye kuramba kune inowedzera kusvibiswa kweDB18C6 kuenzaniswa ne18-korona-inoita kuti zviite kuti zviite kuti zvibodzwa zvinoda kukwirisa. Inogona kushandiswa mukuwedzera-tembiricha, kusanganisira polymerization, organic synthesis, uye zvimwe zvakakwirira-tembiricha maitiro.
Solvent Systems: Sezvambotaurwa, kusuma kweiyo benzene mhete muDB18c6 inovandudza iyo solubility mune isina-polar kana inonhuhwirira solvent system. Ichi chivakwa chinoita kuti ive inobatsira yekushandisa inoda kuti isimbe inyonganiso yemamiriro ekunze.
Zvakawanda, iyo yakasarudzika chimiro uye zvivakwa zveDB18C6 inogonesa huwandu hwakawanda hwekushandisa mukurongedza kwemakemikari, supromolecular chemistry, ion inonzwa, catalinys, uye nzira dzakakwirira-tembiricha. Kugona kwayo kusarudza kusarudza nemamolekora akasiyana siyana uye masimbi ioni anoiita iyo yakakosha yakakoshesa mukutsvaga kwakawanda uye minda yeindasitiri.
